Abstract
The control and measurement of the quantum state of single phosphorus atoms in silicon has opened up vast new
avenues for exploration of quantum effects. The work outlined in this thesis describes the development of several of
these avenues, extending the applications of the system for quantum science. The electron and nuclear states of the
phosphorus donor have been utilised as a quantum memory, experimental means have been developed to optically
address these quantum states, and experiments were developed to probe the nature of causality and time-symmetry
in quantum systems.