Publication:
Synthesis and X-ray crystallographic analysis of chiral pyridyl substituted carbocyclic molecular clefts
Synthesis and X-ray crystallographic analysis of chiral pyridyl substituted carbocyclic molecular clefts
| dc.contributor.author | Rendina, L | en_US |
| dc.contributor.author | Harding, Margaret | en_US |
| dc.contributor.author | Lee, Chun-Cheng | en_US |
| dc.contributor.author | Groneman, J | en_US |
| dc.contributor.author | Turner, Peter | en_US |
| dc.date.accessioned | 2021-11-25T13:30:41Z | |
| dc.date.available | 2021-11-25T13:30:41Z | |
| dc.date.issued | 2006 | en_US |
| dc.description.abstract | Ditopic symmetrical bis(pyridyl) ligands incorporating the chiral dibenzobicyclo[b,f][3.3.1]nona-5a,6a-dieiie-6,12-dione cleft have been synthesised and characterised by NMR spectroscopy, mass spectrometry and X-ray crystallography. The ligands, which incorporate pyridyl groups directly connected to the carbocyclic cleft core or via alkyne or phenyl linkers were accessed from palladium-catalysed coupling reactions of 2,8-dibromodibenzobicyclo[b,f][3.3.1]nona-5a,6a-diene-6,12-dione. X-ray crystal analyses show the interplanar angles between the two cleft aromatic rings in these molecules, which range from 97.80(3) to 109.80(4)degrees. (c) 2006 Elsevier Ltd. All rights reserved. | en_US |
| dc.identifier.issn | 0040-4020 | en_US |
| dc.identifier.uri | http://hdl.handle.net/1959.4/39841 | |
| dc.language | English | |
| dc.language.iso | EN | en_US |
| dc.rights | CC BY-NC-ND 3.0 | en_US |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/au/ | en_US |
| dc.source | Legacy MARC | en_US |
| dc.title | Synthesis and X-ray crystallographic analysis of chiral pyridyl substituted carbocyclic molecular clefts | en_US |
| dc.type | Journal Article | en |
| dcterms.accessRights | metadata only access | |
| dspace.entity.type | Publication | en_US |
| unsw.accessRights.uri | http://purl.org/coar/access_right/c_14cb | |
| unsw.identifier.doiPublisher | http://dx.doi.org/10.1016/j.tet.2006.03.014 | en_US |
| unsw.relation.faculty | Science | |
| unsw.relation.ispartofissue | 20 | en_US |
| unsw.relation.ispartofjournal | Tetrahedron | en_US |
| unsw.relation.ispartofpagefrompageto | 4870-4878 | en_US |
| unsw.relation.ispartofvolume | 62 | en_US |
| unsw.relation.originalPublicationAffiliation | Rendina, L | en_US |
| unsw.relation.originalPublicationAffiliation | Harding, Margaret, Chemistry, Faculty of Science, UNSW | en_US |
| unsw.relation.originalPublicationAffiliation | Lee, Chun-Cheng | en_US |
| unsw.relation.originalPublicationAffiliation | Groneman, J | en_US |
| unsw.relation.originalPublicationAffiliation | Turner, Peter | en_US |
| unsw.relation.school | School of Chemistry | * |