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Single and mixed phase TiO2 powders prepared by excess hydrolysis of titanium alkoxide
Single and mixed phase TiO2 powders prepared by excess hydrolysis of titanium alkoxide
dc.contributor.author | Hanaor, Dorian | en_US |
dc.contributor.author | Karatchevtseva, Inna | en_US |
dc.contributor.author | Chironi, Ilkay | en_US |
dc.contributor.author | Triani, Gerry | en_US |
dc.contributor.author | Sorrell, Charles | en_US |
dc.date.accessioned | 2021-11-25T12:25:02Z | |
dc.date.available | 2021-11-25T12:25:02Z | |
dc.date.issued | 2012 | en_US |
dc.description.abstract | To investigate the excess hydrolysis of titanium alkoxides, TiO2 powders were fabricated from titanium tetraisopropoxide using 6 : 1 and 100 : 1 H2O/Ti (r) ratios. The powders were dried and fired at a range of temperatures ((800uC). Hydroxylation and organic content in powders were characterised using attenuated total reflectance Fourier transform infrared spectroscopy (FTIR), laser Raman microspectroscopy and elemental microanalysis; surface area and pore size distribution were evaluated using N2 gas adsorption; phase composition was analysed using Xray diffraction (XRD) and laser Raman microspectroscopy; and crystallite size was evaluated by XRD, TEM and SEM. Results showed near complete hydrolysis in a predominantly aqueous medium (r5100), resulting in precipitated crystalline powders exhibiting brookite and anatase, which begin to transform to rutile below 500uC. The powders precipitated in a predominantly organic medium (r56) underwent partial hydrolysis, were highly porous and exhibited an amorphous structure, with the crystallisation of anatase occurring at y300uC and the transformation to rutile beginning at 500–600uC. | en_US |
dc.identifier.issn | 1743-6761 | en_US |
dc.identifier.uri | http://hdl.handle.net/1959.4/51780 | |
dc.language | English | |
dc.language.iso | EN | en_US |
dc.rights | CC BY-NC-ND 3.0 | en_US |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/au/ | en_US |
dc.source | Legacy MARC | en_US |
dc.subject.other | Organometallic | en_US |
dc.subject.other | TiO2 | en_US |
dc.subject.other | Hydrolysis | en_US |
dc.subject.other | Powder | en_US |
dc.title | Single and mixed phase TiO2 powders prepared by excess hydrolysis of titanium alkoxide | en_US |
dc.type | Journal Article | en |
dcterms.accessRights | open access | |
dspace.entity.type | Publication | en_US |
unsw.accessRights.uri | https://purl.org/coar/access_right/c_abf2 | |
unsw.description.publisherStatement | Website: www.maney.co.uk | en_US |
unsw.identifier.doiPublisher | http://dx.doi.org/10.1179/1743676111Y.0000000059 | en_US |
unsw.relation.faculty | Science | |
unsw.relation.ispartofissue | 3 | en_US |
unsw.relation.ispartofjournal | Advances in Applied Ceramics | en_US |
unsw.relation.ispartofpagefrompageto | 149-158 | en_US |
unsw.relation.ispartofvolume | 111 | en_US |
unsw.relation.originalPublicationAffiliation | Hanaor, Dorian, Materials Science & Engineering, Faculty of Science, UNSW | en_US |
unsw.relation.originalPublicationAffiliation | Karatchevtseva, Inna, ANSTO | en_US |
unsw.relation.originalPublicationAffiliation | Chironi, Ilkay, ANSTO | en_US |
unsw.relation.originalPublicationAffiliation | Triani, Gerry, ANSTO | en_US |
unsw.relation.originalPublicationAffiliation | Sorrell, Charles, Materials Science & Engineering, Faculty of Science, UNSW | en_US |
unsw.relation.school | School of Materials Science & Engineering | * |
unsw.subject.fieldofresearchcode | 100708 Nanomaterials | en_US |
unsw.subject.fieldofresearchcode | 030306 Synthesis of Materials | en_US |
unsw.subject.fieldofresearchcode | 091201 Ceramics | en_US |
unsw.subject.fieldofresearchcode | 090608 Renewable Power and Energy Systems Engineering (excl. Solar Cells) | en_US |
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