Publication:
Synthesis and hydrolysis of thiol derivatives of molybdocene dichloride incorporating electron-withdrawing substituents
Synthesis and hydrolysis of thiol derivatives of molybdocene dichloride incorporating electron-withdrawing substituents
dc.contributor.author | Waern, J | en_US |
dc.contributor.author | Turner, P | en_US |
dc.contributor.author | Harding, Margaret | en_US |
dc.date.accessioned | 2021-11-25T13:30:43Z | |
dc.date.available | 2021-11-25T13:30:43Z | |
dc.date.issued | 2006 | en_US |
dc.description.abstract | Hydrolysis studies of derivatives of molybdocene dichloride in which the two chloride ligands were replaced by 3,5-bis(trifluoromethyl)thiophenol, 3,5-bis(trifluoromethyl)benzyl thiol, and 2,2,2-trifluoro-ethane thiol ligands confirmed that the electron-withdrawing groups affect the lability of the Mo-S bonds and promote slow generation of the putative biologically active species `Cp<sub>2</sub>Mo<sup>2+</sup>`; the trifluoroethane thiol derivative underwent 50% hydrolysis in 14 h in 10% D<sub>2</sub>O/DMSO-d<sub>6</sub>. The structure of molybdocene bis(S-3,5-bis(trifluoromethyl)benzyl thiol) was confirmed by X-ray crystal structure analysis. © 2006 American Chemical Society. | en_US |
dc.identifier.issn | 0276-7333 | en_US |
dc.identifier.uri | http://hdl.handle.net/1959.4/39843 | |
dc.language | English | |
dc.language.iso | EN | en_US |
dc.rights | CC BY-NC-ND 3.0 | en_US |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/au/ | en_US |
dc.source | Legacy MARC | en_US |
dc.subject.other | Molybdenum compounds | en_US |
dc.subject.other | Derivatives | en_US |
dc.subject.other | Hydrolysis | en_US |
dc.subject.other | Electrons | en_US |
dc.subject.other | Synthesis (chemical | en_US |
dc.subject.other | X ray crystallography | en_US |
dc.subject.other | Chemical bonds | en_US |
dc.title | Synthesis and hydrolysis of thiol derivatives of molybdocene dichloride incorporating electron-withdrawing substituents | en_US |
dc.type | Journal Article | en |
dcterms.accessRights | metadata only access | |
dspace.entity.type | Publication | en_US |
unsw.accessRights.uri | http://purl.org/coar/access_right/c_14cb | |
unsw.identifier.doiPublisher | http://dx.doi.org/10.1021/om060133e | en_US |
unsw.relation.faculty | Science | |
unsw.relation.ispartofissue | 14 | en_US |
unsw.relation.ispartofjournal | Organometallics | en_US |
unsw.relation.ispartofpagefrompageto | 3417-3421 | en_US |
unsw.relation.ispartofvolume | 25 | en_US |
unsw.relation.originalPublicationAffiliation | Waern, J | en_US |
unsw.relation.originalPublicationAffiliation | Turner, P | en_US |
unsw.relation.originalPublicationAffiliation | Harding, Margaret, Chemistry, Faculty of Science, UNSW | en_US |
unsw.relation.school | School of Chemistry | * |