Engineering

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  • (2021) Liu, Huabo
    Thesis
    Due to the large variety and unique physiochemical properties, such as high electrical conductivity, adjustable interlayer spacing, intercalation chemistry and so on, two-dimensional (2D) materials have attracted tremendous attention for their suitability in the development of high-performing supercapacitors. Despite that great progress has been made, there is still no single 2D material that can perfectly meet all the requirements to replace the existing material, mainly activated carbon, used in commercial supercapacitors. Therefore, continuing efforts for exploring novel, high-performing 2D materials with low cost are desirable. In this dissertation, the prior studies on the development of 2D materials ranging from layered inorganic materials to organic-inorganic hybrids for supercapacitors are first reviewed. As an emerging type of 2D material, layered organic-inorganic hybrids start to show promising results to be used to fabricate high-density, nonporous, and thick electrodes for compact capacitive energy storage. However, the studies in this area are still lacking. Thus, the goal here is to explore the opportunities of 2D organic-inorganic hybrids for applications in supercapacitors. The relevant techniques and methods used throughout the study are then outlined. Next, three research chapters supporting the main findings of the investigation are included. The first research chapter describes a facile mechanical strategy to improve the kinetics and rate performance of 2D organic-inorganic hybrid electrodes at ultrahigh mass loadings (up to 30 mg cm-2). The second research chapter reports the synthesis of a new layered organic-inorganic hybrid material with excellent volumetric and areal capacitances even at mass loadings reaching 50 mg cm-2, highlighting the good electrode kinetics. The third research chapter presents the wafer-scale electrochemical deposition synthesis of 2D organic-inorganic composite films with controlled size and thickness, which are promising for the development of flexible and transparent electrochemical energy storage devices. Finally, conclusions and recommendations are given at the end of this dissertation.

  • (2021) Li, Zhiwei
    Thesis
    Cataracts are responsible for almost half of worldwide blindness, making it one of the biggest health challenges in this era. Cataracts are irreversible because of their pathology, which is controlled by the aging and biochemical change of eye tissues. As a result cataract surgery is currently the only effective treatment. The general procedure of cataract surgery includes separation and removal of the failed lens tissue from the surrounding soft tissue in the eye, followed by artificial lens implantation. Lens removal requires successful separation of lens tissues as a critical step that determines surgical success. However key parts of cataract separation affected by fluid mechanics and rheology are uncharacterised. This project aims to explain the behaviors of such separation phenomena and connect fundamentals with possible explanations and enhancements. A multi-layer bio-polymer injection model is developed to mimic the separation process in cataract surgeries. The separation can be considered peeling of a soft elastic tissue by a pressure-driven fluid flow, whose performance is closely related to properties such as flow rate and velocity as well as fluid viscosity, normal stress and yield stress. In our project, the separation physics is studied as a hydraulic fracture problem. Theories are proposed to discuss the effectiveness and safety of hydraulic fracture with different flow and fluid parameters. It is found both higher flow rate and viscosity will cause tissue to be deformed more, which may increase the risks of tissue damage. Yield stress fluids with significant elasticity are not suitable as in most cases they rupture the tissue. Normal stress fluids have the potential to provide safe and effective separation. It is found that with a small scale separation, however, the separation effectiveness is mainly affected by the flow rate, and the fluid properties play a more minor role. General ideas and potential improvements according to our results and theories are also proposed for cataract surgeries, which we hope will contribute to easier and safer separation.

  • (2021) Gresham, Isaac
    Thesis
    Polymer brushes are arrays of densely surface-tethered polymer chains, and are of interest for two reasons. Firstly, they possess interfacial characteristics, such as antifouling and lubrication, that are desirable in many applications. Secondly, they are model systems that can provide additional insight into polymer behaviour due to their unique geometry. Observing the interfacial structure of these brush layers is critically important for understanding both their properties and the mechanisms driving the polymer behaviour. To date, neutron reflectometry (NR) is the only technique that can demonstrably resolve the nanoscale structure of polymer brushes. However, these diffuse interfaces produce subtle features in the reflectometry data that challenge interpretation, with typical analyses failing to quantify the derived structure's uncertainty. Furthermore, the experimental potential of this technique for the study of brushes is only just being realised. This Thesis advances NR as a tool for studying polymer brush systems by establishing a robust analysis methodology that overcomes previous hurdles and demonstrating novel experimental techniques. In both cases, poly(N-isopropylacrylamide) (PNIPAM) brushes are used as model systems. First, the polymer system is characterised through the novel observation of surface-initiated ARGET ATRP using time-resolved NR, and a study of the dry brush as a function of humidity and temperature. Second, methodologies are developed that allow for robust determination of both solvated and confined brush structures. Lastly, NR is used to elucidate the behaviour of PNIPAM brushes in complex environments. A novel confinement apparatus is used to investigate the structure of a PNIPAM brush under mechanical confinement and contrast-variation provides unparalleled insight into PNIPAM–surfactant systems. In each case, complementary techniques are essential in guiding reflectometry experiments and fully understanding the polymer system. This work develops and demonstrates techniques that enhance the study of diffuse interfaces with the NR technique. Moreover, the holistic structural examination of PNIPAM undertaken sheds new light on the phase behaviour of this ostensibly well-understood polymer and highlights its rich interaction with surfactants.

  • (2020) Yan, Yitao
    Thesis
    The rapid development of technology has made the design, monitoring and data storage of large-scale, complex interconnected systems possible. These efficient and economical interconnected systems come with a price: the complex dynamics due to convoluted interconnections make the effective control of such a system incredibly difficult. The behaviour of the subsystems in a network is vastly different than that when it is not, and the inherent uncertainties due to modelling errors may be amplified as a result of the strong interactions. Furthermore, the ability to collect and process large amount of data leads to the paradigm shift from model-centric description to data-centric description or hybrid model/data description of a system. These challenges necessitate the need for a unified foundation for the control of complex systems that is able to admit descriptions of systems not only limited to the conventional differential/difference models. Motivated by these challenges, this thesis aims to develop such a framework for the distributed control of an interconnected system using the behavioural systems theory. As a theory that focuses on analysing the dynamics of the external variables and places the trajectories admissible within the system as the central role of describing a dynamical system, it is perfect for the construction of a platform that unifies various classes of systems and is effective in the analysis of interconnections. The framework is eventually set up as a completely representation-free structure, allowing for free choice of representations for the systems according to the specific needs. Algorithms for several representation structures are also provided. For the case where the subsystems are represented as linear time-invariant differential systems while the global requirements are specified as H-infinity type conditions, the control design follows a two-step algorithm. Firstly, the behaviours of the subsystems, the (to-be-designed) controllers as well as the global requirements are all represented as dissipative dynamical systems with quadratic supply rates, from which the (to-be-determined) controller supply rates can be found. Secondly, parametrisations of the supply rates are carried out to search for linear time-invariant representations for the controllers. Algorithms for subsystems with various types of parametric uncertainties are given to add robustness to the controllers. The resulting framework deals with interconnections, uncertainties in the subsystems and disturbance attenuation simultaneously. For the general framework, neither the subsystems nor the controllers have prescribed representations. The behaviours of the subsystems are denoted by their respective sets of trajectories and interconnections are interpreted entirely as variable sharing instead of signal flows. Furthermore, the network of an interconnected system is also defined as a dynamical system with its own behaviour, leading to a generic, scalable and flexible representation of the interconnected behaviour. From this structure, necessary and sufficient conditions for the existence of the controller behaviours can be given and all distributed controller behaviours can be constructed explicitly. This framework unites various representations and descriptions of the features of dynamical systems as behaviours, thereby allowing for the formation of a hybrid platform for the analysis and distributed control generically and systematically.

  • (2020) Wu, Chenyu
    Thesis
    Photo-controlled polymerisation uses a photo-excited photocatalyst (PC) to reversibly and deactivate the propagating species. Under regulation by light, photo-controlled polymerisation features temporal control, spatial control, sequence control and high level of selectivity/orthogonality between different systems, leading to a range of applications in advanced macromolecular synthesis such as surface patterning, 3D/4D printing, polymeric micelles, multiblock antimicrobial polymers with precise sequences and architectures. All these unique features of photo-controlled polymerisation are largely dependent on properties and functionalities of PCs. Traditionally, the selection and discovery of appropriate PCs rely heavily on a trail-and-error approach, where extensive experimental screening is needed to identify desired candidates. To reduce costs and circumvent the challenges in laborious experimental work, a rational design strategy emerged where a new PC in application to a photo-controlled polymerisation system can be designed based on understanding of the structure-property-performance relationships. This dissertation aims to enable and streamline a general fully computer-guided rational strategy of designing an efficient and functional PC for a commonly used photocontrolled polymerisation technique, namely photoinduced electron/energy reversible addition-fragmentation chain transfer (PET-RAFT) polymerisation. This thesis starts from using naturally evolved Chl a with various functional substituents and investigating its photocatalytic performance and functionalities in PET-RAFT polymerisation. General orientations for the design of PET-RAFT PCs were inspired from this natural design. On top of this, comprehensive structure-property-performance relationships were established at the quantum chemical level as guiding principles for rational PC design of PET-RAFT polymerisation, by combining experimental and computational studies on a library of halogenated xanthene dyes. Finally, by implementing the most cutting-edged quantum chemical software packages, the fully computer-guided strategy of functional PC design for PET-RAFT polymerisation was enabled based on broadened structure-property-performance relationships. As an example, an efficient pH-switchable organic PC was designed. Application of this rationally designed PC in PET-RAFT polymerisation resulted in the first organocatalysed pH and light dual-gated controlled polymerisation.

  • (2020) Xie, Zhirun
    Thesis
    Solar energy conversion efficiency can be determined by the properties of a photocatalyst. Recently, bismuth vanadate (BiVO4) has emerged as a potential photocatalyst due to its suitable band structure and superior visible light response. However, severe charge recombination, poor electron transportation and sluggish surface reaction kinetics prevent BiVO4 from reaching its potential. Herein, different tactics regarding its modification were employed to improve the photocatalytic capability of BiVO4. The research initially investigated the interfacial contact between BiVO4 and reduced graphene oxide (rGO). Two BiVO4/rGO composites with BiVO4 particles extensively or insufficiently contacted with rGO sheets were fabricated. An enlarged interfacial contact greatly improved charge separation and electron transfer efficiency as well as band alignment within the BiVO4/rGO composite, hence delivering a greater photocurrent during photoelectrochemical (PEC) testing. However, an excessive rGO coverage also resulted in higher hydrophobicity, which reduced the water miscibility and lowered the capability toward photocatalytic O2 production. Consequently, the balance between electron shuttling and the water miscibility should be considered depending on the photoreaction mode. Subsequently, a CoOx co-catalyst was loaded onto a dual-faceted BiVO4 which possessed distinct levels of exposed {010} and {110} facets. Enhancement provided by the co-catalyst was depended on both its deposit location and the ratio of {010}/{110} facet exposure. When selectively deposited on the hole-accumulating {110} facet or loaded on {010}-dominant BiVO4 particles, CoOx functioned more effectively in alleviating surface hole trapping and reducing the charge recombination, thus delivering a higher photocatalytic activity. Finally, the bimetallic phosphide, NiFePx, was studied as a BiVO4 co-catalyst for PEC performance. NiFePx was immobilized onto a BiVO4 photoanode via a hydrothermal method followed by a phosphorization process. The NiFePx passivated the surface states of BiVO4 and provided a greater driving force to initiate water oxidation. Accordingly, surface charge recombination was suppressed, and charge transfer and charge injection efficiency were promoted. In summary, surface modification strategies can endow BiVO4-based photocatalysts with a good capacity for water splitting with rational manipulation of their interfacial properties providing even greater benefits.

  • (2020) Lu, Xinxin
    Thesis
    Photocatalytic water splitting to produce H2 fuel has drawn considerable attention due to ever-increasing environmental concerns and the rising global energy demand for renewable and clean energy formation. Since last century, the semiconductor photocatalysts have been studying to explore their photocatalytic properties for solar-driven H2 evolution from water. Among the various H2-evolving photocatalysts, CdS with excellent visible-light absorption and suitable band potentials is one of the most studied photocatalysts. Although cocatalyst-decorated CdS nanorods (NRs) offer a promising H2 evolution performance, further benefits invoked by spatial cocatalyst decoration are worth exploring. Given that noble metal cocatalysts were most deposited on the tips of CdS NRs, the tip deposition of non-noble metal cocatalysts on CdS NRs was explored in the first stage of PhD research. For the first time, it was found that amorphous MoOxSy preferentially photodeposited on CdS NR tips, which enhanced photocatalytic H2 evolution. Detailed characterization and studies determined the composition and possible formation pathways of the amorphous MoOxSy on the CdS tips. The enhancement was ascribed to the effective trapping of photoinduced electrons by the MoOxSy resulting from its lower surface work function compared to CdS. However, amorphous MoOxSy is unstable in most hole scavengers except methanol. Consequently, the MoOxSy was vulcanized into MoS2, with MoS2 presenting either on the only tips, on the tips and random walls, or having an overall coating. MoS2-tipped CdS NRs exhibited a better H2 evolution activity compared to other MoS2-loaded CdS NRs. Kelvin probe force microscopy and time-resolved photoluminescence spectroscopy were used to study spatial charge separation, transfer, and lifetime. The superior photoactivity of MoS2-tipped CdS NRs was assigned to spatially intensified charge separation along the long axis of NRs, thereby lowering the charge recombination rate. To further understand the effects of MoS2 distribution on CdS NRs, MoS2 was parallelly or perpendicularly placed on polar CdS (001) surfaces (representing CdS NR tips) and non-polar CdS (110) surface (representing CdS NR wall) to construct different CdS/MoS2 models for DFT calculations. It was verified that CdS NR is capable of the longitudinal charge transfer due to charge polarization on polar (001) surfaces. The distinct electronic properties (i.e. shift in core-level energies of Cd and S orbitals, interfacial charge accumulation and depletion) of different CdS/MoS2 heterostructures, induced by the different interfacial bonding arrangements and MoS2 orientation, were observed and analyzed. In addition, two types of MoS2-loaded CdS NRs (MoS2 being only on the tips or only on the walls of CdS NRs) were fabricated to obtain their BEs of Cd 3d and S 2p by XPS for comparison, which is consistent with the expected DFT results. The band edges of CdS component in the as-prepared samples were also determined by combining Tauc plots and VB XPS measurements; the band shifts in experiments approximately correspond to DFT results. As a result, the MoS2 distribution and orientation affect the electronic properties of CdS/MoS2 heterostructures and thereby giving a different photoactivity. Overall, this thesis reveals that the origins of photocatalytic H2 evolution advantages induced by spatially located cocatalyst and gives insights into the activity enhancement mechanism for tip-decorated CdS NRs, which guides the construction of more efficient CdS-based photocatalysts.

  • (2020) Zhang, Qingran
    Thesis
    Electrochemical energy conversion systems are capable of storing renewable energy in chemical forms which could be subsequently used as fuels or chemical feedstocks. Electrocatalytic reactions are cornerstones of these electrochemical processes and play pivotal roles in determining the overall efficiency of various electrolysis systems. For instance, the oxygen evolution reaction (OER) liberates the electrons and protons for the generation of clean hydrogen (H2) fuel through the hydrogen evolution reaction (HER) in an electrolytic water splitting system integrated with renewable power supplies. In addition, the oxygen reduction reaction (ORR) enables the energy and chemical conversions in fuel cells, metal-air batteries and electro-synthesis of hydrogen peroxide, satisfying our pursuit of a green chemistry. The main obstacle for the large-scale implementation of these energy conversion systems is the sluggish reaction kinetics on both the anodes and the cathodes, including anodic OER, cathodic HER and ORR, which require noble-metal-based electrocatalysts to expedite the reaction at a desirable rate and selectivity (e.g. IrOx and RuO2 for OER, Pt/C for ORR and PtHg for H2O2 production). However, the high cost and poor stability of these noble-metal-containing materials severely hamper their commercial viability. In these regards, the rational design of non-noble-metal electrocatalysts with high activity, good durability, desirable selectivity and low cost is highly sought after. This thesis focuses on the screening, design, synthesis and characterization of first-row transition-metal-based materials as efficient electrocatalysts for various electrolysis systems. To resolve the activity and stability issues haunted by water electrolysis system, two kinds of nanostructured bifunctional HER-OER electrocatalyst are fabricated including (1) ultrathin Fe-N-C nanosheets coordinated Fe-doped CoNi alloy nanoparticles and (2) defective FeCoNi (oxy)hydroxide atomic layers, which aim at an improved catalytic performance and long-term durability. Besides, ORR is the bottleneck of not only fuel cells and metal-air batteries but also other devices targeting at a continuous production of H2O2. To this end, another two novel electrocatalysts are synthesized: (1) epoxy-modified carbon nanotubes with isolated Co atomic sites and (2) thin Cu layer decorated Co nanoparticles encapsulated by a Co-Nx/Cu-Nx co-doped carbon, both achieving a high selectivity in different pathways with excellent activity. New preparation techniques are developed to fabricate these catalysts, and their catalytic properties are evaluated by electrochemical measurements. The structural and chemical properties of catalysts down to atomic scale are also investigated with a variety of physical characterizations (e.g. X-ray adsorption spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, transmission electron microscopy). The correlations established between activity and structural properties give insights into the origin of activity/selectivity within these composites. Last but not the least, the results indicated that, through rational design, transition-metal-based electrocatalysts with high activity, long-term durability and desirable selectivity even superior to the noble metal benchmarks can be achieved with an apparently lower manufacturing cost.

  • (2021) Elhalis, Hosam
    Thesis
    This thesis investigated the ecology and metabolism of microorganisms, especially yeasts, during the wet fermentation of Australian coffee beans, and their contribution to coffee quality. Pulped coffee beans were fermented underwater for 36 h where yeast growth was suppressed by the addition of Natamycin at 300 mg/L. Spontaneous fermentation without the addition of Natamycin was conducted as control. The growth and diversity of microorganisms during fermentation were monitored by both culture dependent and independent methods. Major non-volatile metabolites during fermentation were monitored by high performance liquid chromatography (HPLC) and volatiles in the green and roasted beans were measured by solid phase microextraction coupled with gas chromatography tandem mass spectrometry (SPME GC-MS). Both bacteria and yeasts grew significantly during spontaneous fermentation while yeast growth was restricted in the Natamycin treated fermentation without significant impact on bacterial growth. The bacterial community was dominated by Citrobacter sp., Gluconobacter cerinus, Leuconostoc mesenteroides and Lactococcus lactis with maximum populations between 4-7.2 log CFU/g, while Hanseniaspora uvarum and Pichia kudriavzevii were the predominant yeasts at 4.5-5 CFU/g. During fermentation, the microflora utilized sugars in the mucilage and produced mannitol, glycerol and essential volatiles, mainly alcohols, esters, aldehydes and organic acids, with their concentrations generally lower in beans fermented with yeast suppression. Coffee produced from yeast suppressed fermentation received lower sensory scores in flavour and aroma and overall quality by 3 Q-Grade coffee masters. When H. uvarum and P. kudriavzevii were inoculated individually and in combination, they dominated the fermentation by growing to 9-10 log CFU/ml, and produced greater amounts of glycerol and flavour volatiles in the green beans which remained in higher levels after roasting compared with the control. Coffee brewed from these beans received significantly high scores of flavour, aroma, acidity and overall quality. Mucilage degradation seems to be initiated by endogenous enzymes and microbial contributions to the process occurred subsequently either enzymatically or by acidification. These findings demonstrated the crucial contribution of yeasts to successful coffee fermentation and high-quality coffee, and the potential of developing the two yeasts into starter cultures for coffee fermentation.

  • (2020) Rezaeimotlagh, Adel
    Thesis
    Although conventional thermal processing ensures the microbial safety of liquid foods, it adversely affects the nutritional and organoleptic properties of these food products. Hence, the application of radio frequency electric fields (RFEF) processing, as a non-thermal alternative, has been investigated in the past few decades for liquid foods. This research was conducted to study the effect of RFEF processing on liquid foods in three main aspects. In the engineering aspect, Computational Fluid Dynamics (CFD) models were utilised to assess the effect of inserting stainless steel mesh in a co-linear chamber on process homogeneity, in comparison to a no-mesh co-linear configuration. The results indicated that the insertion of a stainless steel mesh in a co-linear configuration enhanced the homogeneity of the process by improving the electric field, temperature, and velocity profiles within the chamber. In the microbiological aspect, the effect of various RFEF processing parameters, such as electric field, temperature, frequency, and treatment time, on microbial inactivation was studied. In cranberry juice, an E.coli inactivation level of 6.57±0.02 logCFU mL-1 was achieved by multiple-stage RFEF processing with an electric field, outlet temperature, and treatment time of 13.2 kV cm-1, 40 °C, and 3240 μs, respectively. Also, based on inactivation results, a kinetic inactivation model as a function of the electric field, temperature, and treatment time was developed. In orange juice, multiple-stage RFEF processing with an electric field, temperature, treatment time of 11.7 kV cm-1, 42 °C, and 1.17×10-3 seconds, respectively, extended the shelf-life compared to the control sample. Lowering the frequency from 20 to 10 kHz increased the inactivation of E.coli in saline water with a peak at 12.5 kHz, and a further decrease in frequencies below 10 kHz reduced the inactivation levels due to electrolysis. A synergistic effect on E.coli inactivation was achieved when low frequency (LF) electric fields processing of above 9.6 kV cm-1 was combined with high frequency (HF) processing with outlet temperature and power above 55 °C and 739 W, respectively. In the nutritional aspect, a comparison study between multiple-stage RFEF processing with an electric field, temperature, and treatment time of 11.7 kV cm-1, 42 °C, and 1.17×10-3 s, and a heat processing with similar inactivation level referred to as thermal processing (81.5 °C for 10 s), and an industrial level heat processing, referred to as pasteurisation processing (90 °C for 30 s), during 45 days of storage at 4 °C, was conducted. The results obtained after the storage indicated that although a higher antioxidant capacity and vitamin C content were achieved in orange juice processed by RFEF compared to pasteurisation processing, the thermal processing resulted in the highest level of antioxidant capacity and vitamin C content in orange juice. Furthermore, regarding total phenolic compounds (TPC), orange juice processed by RFEF has the lowest content of TPC compared to both heat treatments. In conclusion, the RFEF processing demonstrated considerable potential as an alternative to conventional heat treatment, especially in the microbiological aspect. However, further investigations on the effect of RFEF processing parameters, such as electric field and temperature, on nutritional and organoleptic properties of liquid foods are required. These investigations can be complemented by cost analysis studies, which can help to advance RFEF processing towards commercialisation.