Filters
Availability
Publication Year
Resource Type
Faculty
School/Institute
Publication Search Results
Sort
Results per page
1 - 2 of 2
-
(2006)Journal ArticleThe sequestration of CO2 as a greenhouse mitigation option is becoming an increasingly important priority for industry. Theoretically membrane based CO2 removal systems have the potential to provide a cost effective, low maintenance approach for removing CO2 from gas streams. This study examines the effect of membrane characteristics, operating parameters and system design on sequestration costs for any source-sink combination. The total sequestration cost per tonne of CO2 avoided for separation, transport and storage are compared for the separation of CO2 from a black coalfired power plant in Australia. The results show that the membranes currently available have a total sequestration cost of US$55-61/tonne CO2 avoided. Lower costs for CO2 avoided can be achieved using an MEA amine based absorption separation system. Gas separation membranes would require significant improvements in CO2 permeability and selectivity, together with reductions in the cost of membranes and changes to the process configurations and operating pressures to be competitive against MEA systems for the purposes of geo-sequestration.
-
(2011)Journal ArticleThick anatase films were fabricated on graphite substrates using a method of anodic aqueous electrophoretic-deposition using oxalic acid as a dispersant. Thick films were subsequently fired in air and in nitrogen at a range of temperatures. The morphology and phase composition were assessed and the photocatalytic performance was examined by the inactivation of Escherichia coli in water. It was found that the transformation of anatase to rutile is enhanced by the presence of a graphite substrate through reduction effects. The use of a nitrogen atmosphere allows higher firing temperatures, results in less cracking of the films and yields superior bactericidal performance in comparison with firing in air. The beneficial effects of a nitrogen firing atmosphere on the photocatalytic performance of the material are likely to be a result of the diffusion of nitrogen and carbon into the TiO2 lattice and the consequent creation of new valence band states.