Engineering

Publication Search Results

Now showing 1 - 10 of 247

  • (1998) Turner, I.L.; Tomlinson, R.B.; Watson, M.
    Report

  • (1998) Couriel, E.D.; Cox, D.R.; Horton, P.R.
    Report


  • (1997) Peters, G; Maher, WA; Barford, JP; Gomes, VG
    Journal Article
    Selenium (Se) is a contaminant of concern in environments affected by discharges from smelting and coal-burning industries. Experiments have been performed to investigate the phase associations of selenium in contaminated sediments under a range of controlled redox conditions. In this study, Se sediment associations were examined using the BCR sequential extraction technique after stabilisation at different redox states. It was shown that although most of the sediment-bound Se is associated with the operationally-defined "organic/sulfide" fraction, as the measured redox potential of the system is increased, more Se moves into the "exchangeable" and "iron/manganese oxyhydroxide" fractions. In these fractions, contaminants can be expected to be more bioavailable. As the mass of Se absorbed to sediments is typically at least an order of magnitude higher than the mass dissolved in porewaters, significant Se exposure may result from oxidative shifts in Se sediment associations.

  • (1999) Peters, G; Maher, WA; Jolley, D; Carroll, BI; Jenkinson, AV; McOrist, GD
    Journal Article
    This paper examines the history of selenium pollution in Lake Macquarie, NSW, Australia, and three factors that may affect the redistribution and remobilisation of particle bound selenium: changes in redox state, bioturbation, and bioaccumulation by macrobenthos and bacteria. Sediment cores were taken from Nords Wharf, a relatively unpolluted area, and from Mannering Bay near the Vales Point coal-fired power station. The age profile at the unpolluted site seems to indicate that mild selenium pollution has been occurring for over 100 years, however, some mixing of the sediments has occurred. At the polluted site, the age profile indicated that major contamination has occurred in the last 30 years, due to an ash dam associated with nearby electric power generation facilities. The contamination chronology suggests that remobilisation and reduction processes have affected the selenium profile. Changing the redox state of Lake Macquarie sediment results in a release of selenium under oxidising conditions and immobilisation under reducing conditions. The sediment-bound selenium was associated with the operationally defined `organic/sulfide' fraction under reducing conditions, and as the redox potential increases this moves into the `exchangeable' and `iron/manganese oxyhydroxide' phases to a limited extent. Bioturbation by the animals Marphysa sanguinea and Spisula trigonella caused increases in the redox potential and pore water selenium concentrations in surfcial sediments relative to unbioturbated controls. Both animals accumulated significantly more selenium when exposed to contaminated sediment than when exposed to uncontaminated control sediments. Selenium concentrations in molluscs from Mannering Bay were all significantly higher than those collected from Nords Wharf. Most of the selenium in the mollusc tissues was found to be associated with the protein fraction. Selenium isolated from hydrolysed muscle tissue was not present as selenate or selenite but as selenomethionine and an unidentified compound. Seven types of bacteria were isolated from Lake Macquarie sediment. All seven isolates were able to transform selenite quantitatively to elemental selenium as evidenced by a red precipitate and identified by X-ray diffraction. Six isolates grew on media containing selenate but no elemental selenium was formed. Mass balances showed that for three isolates total selenium was conserved, selenate decreased and selenium (0; II-) increased indicating the production of non-volatile organic selenium compounds. For two isolates both total selenium and selenate decreased with no increase in selenium (0; II-), therefore, loss of selenium occurred from the media. Selenium is immobile in anoxic reduced sediments but may become available to benthos and fish as a consequence of sediment oxidation associated with bioturbation leading to bioaccumulation and transformation by macrobenthos and bacteria. These mechanisms can be invoked as possible transport pathways to explain the presence of selenium above background concentrations in preindustrial sediments, but further work dating the sediments in which elevated concentrations of selenium are found is needed to confirm this hypothesis.

  • (1997) Nobbs, Denis M.; Barford, John P.; Carroll, Brett I.; Peters, Gregory M.
    Journal Article
    Lake Macquarie, an estuarine lake on Australia's eastern seaboard, has been subject for almost a century to anthropogenic contamination by heavy metals and metalloids, including selenium, arising from industrial sources including a lead-zinc smelter, coal-fired power stations and sewage works. , Selenium tissue concentrations in fish from the Lake have recently been reported at up to twelve times those recommended for human consumption. This paper describes an integrated investigation into selenium contamination in the Lake over a four-year period. One key component of these investigations is the ability of indigenous micro-organisms to reduce selenium in estuarine sediments from higher to lower oxidation states, therefore immobilising or volatilising it, and the use of this in the treatment of industrial wastewaters or potentially the in-situ bioremediation of contaminated sediments. A second key component is a study of the mechanisms controlling sediment-stored selenium concentrations and the extent to which they can be influenced by bioturbative organisms. Integrated into these two broad areas and described here are a number of related investigations into: bioavailability of sediment-bound selenium; computer modelling of selenium biogeochemistry; representation of heavy metal data in a GIS format; and determination of the specific historical contributions of a power station to selenium loads in the Lake. Through this integrated approach we have built on synergies between the separate components of our research program to add to our understanding of the nature of selenium biogeochemistry in the Lake and to propose potential bioremediation strategies for both the Lake and contaminated industrial wastewaters or surface water.

  • (1999) Peters, G; Maher, WA; Krikowa, F; Roach, AC; Jeswani, HK; Barford, JP; Gomes, VG; Reible, DD
    Journal Article
    Measurements of selenium in sediments and benthic infauna of Lake Macquarie, an estuary on the east coast of Australia, indicate that sediments are a significant source of selenium in the lake's food web. Analysis of surficial sediment samples indicated higher selenium con- concentrations near what are believed to be the main industrial sources of selenium to the lake: a smelter and a power station. Sediment cores taken from sediments in Mannering Bay, near a power station at Vales Point, contained an average of 12 times more selenium in surficial sections than sediment cores from Nord's Wharf, a part of the lake remote from direct inputs of selenium. The highest selenium concentration found in Mannering Bay sediments (17.2 mg/g) was 69 times the apparent background concentration at Nord's Wharf (0.25 mg/g). Pore water concentrations in Mannering Bay were also high, up to 5 mg/l compared to those at Nord's Wharf which were below detection limits (0.2 mg/l). Selenium concentrations in muscle tissues of three benthic-feeding fish species (Mugil cephalus, Platycephalus fuscus, Acanthopagrus australis) were significantly correlated ( p < 0:05) with surficial sediment selenium concentra- tion. Selenium concentrations in polychaetes and molluscs of Mannering Bay were up to 58 times higher than those from Nord's Wharf. Two benthic organisms, the eunicid polychaete Marphysa sanguinea and the bivalve mollusc Spisula trigonella, were maintained at different densities in selenium-spiked sediments. Both animals accumulated selenium from the spiked sediment, confirming that bioaccumulation from contaminated sediments occurs. Collectively, these data suggest that benthic food webs are important sources of selenium to the fish of Lake Macquarie.

  • (1999) Bandyopadhyay, Srikanta; Gowripalan, Nadarajah; Rizkalla, S; Dutta, P; Bhattacharyya, D
    Conference Paper

  • (1995) Han, Shaowei; Gu, Genda; Zhao, Yong; Russell, Graeme; Koshizuka, N
    Journal Article
    Two types of Bi-2212 single crystals, one type having a low T c and the other having a high T¢ were annealed in air at different temperatures over the range 450°C to 750°C followed by furnace cooling. The transition temperature of the crystals with low T c (~ 56 K) increased with increase of annealing temperature, while the crystals with high Tc (~ 91 K) had just the opposite behaviour under the same annealing conditions. It is indicated that the quality of as-grown crystal has a significant effect on the superconducting properties of the annealed crystal. The c-axis values for both types of crystals decreased with increase of annealing temperature. According to the relationship between c-axis values and the oxygen content, our results confirmed the existence of a dome-shaped curve of T¢ with carrier concentration in Bi-2212 single crystal similar to that in Bi-2212 compound reported previously by Groen and de Leeuw [Physica C 159 (1989) 417]. By studying the increase of annealing time at a fixed temperature of 650°C, T¢ and ATe were found to change very little for both types of crystals. Thus, T c and AT~ were more sensitive to annealing temperature than to annealing time. XRD, SEM and EDS revealed that a small quantity of powder phase appeared after annealing at temperatures above 500°C for both types of crystals. This powder phase had the Bi-2212 composition, which indicated that the integrity of the Bi-2212 single crystals was significantly degraded by the annealing process.