Publication Search Results

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  • (2020) Khayyam Nekouei, Sayyed Rasoul
    Electronic waste (e-waste) has become an urgent issue in digitally dependent world, owing to the unprecedented use of electronic devices, and this has compelled the world to develop new techniques to recycle such wastes. Printed Circuit Boards (PCBs), one of the most complex components of e-waste, contain different metallic, polymeric, and ceramic components. Recycling of waste PCBs (WPCBs) is a critical issue from both aspects of hazardous waste management and recovery of valuable resources. Direct transformation of e-wastes into value-added materials helps to conserve resources and at the same time prevents the environmental impacts of conventional disposal. Consequently, during the course of this project, the primary purpose was improving the recycling of WPCBs by valorizing and transforming them into high value-added products, such as nanostructured alloy and nanopowders. Regarding the zero-waste approach, eight separate phases were followed: In phase 1, a mechanical-physical separation method for recovery of metallic elements of WPCB without any chemical or/and thermal processes was introduced. Two milling stages were applied to enhance the liberation degree, followed by a physical flotation process for enrichment. In phase 2, solid-state mechanical alloying was used to directly convert crushed WPCB to a homogenous nanostructured alloy (Cu79-Zn13-Fe3-Sn3-Ni1). The nanopowder was successfully applied in nanofluid application. In phase 3, an effective statistical tool was taken to optimize the recovery of metal content (i.e., Cu, Fe, Zn, Pb, Ni, Sn, and Al) embedded in crushed WPCB using a leaching agent without any additive or oxidative agent. In phase 4, the polymeric residue left from the leaching process was used as the source of carbon in the reduction of iron oxide from electric arc furnace (EAF) slag in steelmaking. Hence, two problematic and complex waste streams were successfully converted to a clean alloy. In phase 5, Sn content of the leaching solution was directly transformed into high surface area t-SnO2 nanoparticles (NPs). The synthesized NPs successfully removed dye pollutants from simulated industrial wastewater. In this way, one waste material was used to remove another. In phase 6, using ion-exchange (adsorption/desorption) technique, heavy metals (Cu, Zn, Ni, and Pb), and Al were selectively recovered and separated. In phase 7, the Cu content of the leaching solution was electrodeposited as trilayer thin films for energy storage (supercapacitor) and energy harvesting (renewable solar water splitting) applications. Finally, in phase 8, the environmental and economic impacts of the thin film production process assessed using Life Cycle Assessment (LCA) approach.

  • (2022) Biswal, Smitirupa
    The iron and steel industry is one of the prominent industrial sectors in the world since steel is a vital material with a wide range of applications in our daily lives. There will be a gradual improvement in the living standards, infrastructure and economic growth of developing nations with time. All these will necessitate the demand for steel, and it is essential to meet the same but in an environmentally friendly and sustainable way. The ferrous industries are associated with various issues like extensive greenhouse gas emissions, energy-intensive processes and heavy reliance on fossil fuels and natural resources. At the same time, concern regarding waste generation and its management is taking up the momentum and calls are being made for recycling and green recovery. Reuse of waste materials in the manufacturing process could make the industries circular economy resilient. The Ph.D. research work is based on this notion and involves a novel approach of utilizing a bio-based waste material called spent coffee grounds (SCGs) for application in ironmaking. The research work involved the use of SCGs to produce iron from iron oxide as an alternative to coal/coke. Thermal transformation study of SCGs were carried out in the temperature range of 400 °C to 900 °C. The transformed sample obtained at 400 °C, called T-SCGS (transformed-spent coffee grounds), was preferred for the reduction study in the research work due to presence of optimal amount of volatile matter and fixed carbon. This observation was further validated with better high temperature reduction performance in comparison with metallurgical coke (MC) and SCGs (as-received form). Detailed study regarding solid-state (800-1200 °C) and molten-state (1550 °C) reduction processes were carried out with no-flux and fluxed composite pellets of iron oxide and T-SCGs. Use of T-SCGs for iron recovery from electric arc furnace (EAF) slag was also studied. T-SCGs have both hydrogen and carbon in their molecular structure and reaction of in-situ hydrogen with iron oxide will release the by-product of H2O therefore, helping in reduction of CO2 emissions. Hydrogen is known to be a kinetically better reducing agent than carbon thus, improving reaction efficiency and decreasing energy consumption. Overall, the waste source of SCGs when transformed to a suitable form has the potential to be used as an alternative to coal/coke for sustainable iron production such as in solid-state direct reduction as well as smelting reduction processes and also aiding in the novel concept of circular economy.

  • (2023) Hemati, Sepideh
    The increasing production and disposal of end-of-life vehicles (ELVs) pose considerable environmental challenges due to the pollutants emitted throughout their lifecycle. Automotive shredder residue (ASR), the residual waste after de-pollution and dismantling of automobiles, contains diverse materials, including valuable metals, requiring economic recycling and efficient recovery techniques. This research evaluates an innovative route of selective thermal transformation of ASR and waste glass to produce nano-silicon carbide (SiC), a metallic fraction as byproducts. Furthermore, it focuses on recovering metal values by thermal transformation of ASR into high-value products. The study comprehensively investigates the thermal transformation processes to extract metals and produce valuable metallurgical compounds from ASR. The research highlights the economic and environmental benefits of the proposed transformation process, paving the way for sustainable recycling practices of ASR and reducing reliance on primary sources. The kinetics of SiC synthesis from ASR and waste glass were assessed, and the insights demonstrated significant energy savings compared to traditional methods. The understanding of the SiC formation kinetics from ASR and waste glass served to be helpful in examining the nature of the reaction and controlling variables determining the rate kinetics of decomposition of the reactant. In addition, a potential method of utilising metallic fractions derived from ASR in micromanufacturing is explored. The metallic fraction, rich in Fe, Cu, Al, Ca, and Si, was used as the feed material to develop a metallic alloy for contemporary applications. The valorisation route revealed promising results of recovering the metal fraction from ASR, thereby facilitating the development of different alloys with remarkable properties from secondary sources.